MySQL - SOMME d'un groupe de différences de temps

Select  SEC_TO_TIME(SUM(TIME_TO_SEC(timediff(timeOut, timeIn)))) AS totalhours
FROM volHours 
WHERE username = 'skolcz'

Sinon, peut-être :

Select  SEC_TO_TIME(SELECT SUM(TIME_TO_SEC(timediff(timeOut, timeIn))) 
FROM volHours 
WHERE username = 'skolcz') as totalhours